土壤水溶性盐基离子的高光谱反演模型及验证

土壤水溶性盐基离子是诊断土壤盐渍化类型与盐渍化程度的重要依据,利用光谱技术快速获取土壤水溶性盐基离子含量数据,可为土壤盐渍化类型与盐渍化程度的诊断提供新的技术和手段。该研究通过采集新疆5个不同地区399个土样的反射率与水溶性盐基离子数据并进行31种光谱预处理方法,分析了不同水溶性盐基离子(HCO3-、Cl-、SO42-、K+、Na+、Ca2+、Mg2+)与高光谱反射率之间的相关性;采用K-S(Kennard-Stone)方法挑选出299个样品,针对每种离子使用偏最小二乘回归(partial least squares regression,PLSR)分别建立32个高光谱定量反演模型,优选最佳反演模型,并单独使用100个样品对估测模型进行检验。结果表明:不同离子的最佳反演模型所使用的预处理方法存在差异,其中仅有Cl-和Ca2+、SO42-和Mg2+所使用的预处理方法相同,其他离子则不同;不同离子的反演精度也不同,HCO3-和Ca2+构建的模型相对分析误差(relative percent deviation,RPD)分别为2.67、2.57,模型具有很好的预测能力。Cl-、SO42-和Mg2+所构建的模型RPD分别为2.05、2.10和2.14,表明这三者建立的模型具有较好的预测能力。K+建立的模型RPD仅为1.11,不能对样品进行预测。Na+构建的模型RPD为1.83,表明该离子所建模型只能对样品进行粗略估测。研究结果为探究水溶性盐基离子的高光谱反演增添了新的内容,为土壤盐渍化监测的深入和推进提供了新的思路和方法。     

Interactions between earthworms, trees, soil nutrition and metal mobility in amended Pb/Zn mine tailings from Guangdong, China

This paper reports research that attempts to rehabilitate toxic Pb/Zn mine tailings, in Guangdong, China, to achieve a healthy functional soil that supports sustainable vegetation. We studied the effects of the earthworm Pheretima guillelmi on the growth of a woody legume Leucaena leucocephala on Pb/Zn mine tailings diluted with varying amounts of mineral soil in pot experiments. L. leucocephala grew successfully on tailings with a 25% (w/w) soil amendment, but P. guillelmi only survived and actively burrowed with a 50% soil amendment. The presence of earthworms improved the yield of plants by 10-30%. Whilst earthworms marginally increased available N and P in soil, they increased uptake of phosphorus (by about 10%) to above-ground plant tissues. Six-month-old plants were more sensitive than 10-month plants to metal stress. P. guillelmi increased bioavailable metal concentrations in the amended spoils, accompanied by a direct increase of metal uptake by the plants. Increased metal uptake by plants was largely due to the higher dry matter production stimulated by earthworm activity, but this increased the rate of metal uptake into plants from spoil by at least 16% and as much as 53%. These results demonstrate that we should broaden the ecological context of phytoremediation by considering the plant-soil-animal interactions that influence metal mobility.     

Seawater causes rapid trace metal mobilisation in coastal lowland acid sulfate soils: Implications of sea level rise for water quality

Coastal floodplains are highly vulnerable to inundation with saline water and the likelihood of inundation will increase with sea level rise. Sediment samples from floodplains containing coastal lowland acid sulfate soils (CLASS) in eastern Australia were subjected to increasing seawater concentration to examine the probable effects of sea level rise on acidity and metal desorption. Ten soils were mixed with synthetic seawater concentrations varying from 0% to 100% at a solid:solution ratio of 1:10 for 4 h. There was a slight decrease in pH (≈ 0.5 units) with increasing seawater concentration following treatment, yet, calculated acidity increased significantly. In most soil treatments, Al was the dominant component of the calculated acidity pool. Al dominated the exchange complex in the CLASS and, correspondingly, was the major metal ion desorbed. In general, concentrations of soluble and exchangeable Al, Fe²⁺, Ni, Mn and Zn in all soil extracts increased with increasing salinity. Increasing trace metal concentrations with increasing seawater concentration is attributed to the combined effects of exchange processes and acidity. The increasing ionic strength of the seawater treatments displaces trace metals and protons adsorbed on sediments, causing an initial decrease in pH. Hydrolysis of desorbed acidic metal cations can further contribute to acidity and increase mobilisation of trace metals. These findings imply that saline inundation of CLASS environments, even by relatively brackish water may cause rapid, shorter-term water quality changes and a pulse release of acidity due to desorption of acidic metal cations.     

Critical body residues (CBRs) for ecotoxicological soil quality assessment: copper in earthworms

The term ‘critical body residue’ (CBR) was defined as the lowest observed total body concentration of a contaminant in an organism, which is associated with the occurrence of adverse toxic effects in either individuals or populations of a defined age or stage of development. In this study, internal toxicity thresholds were determined for copper in the clitellated adult stage of earthworms (Lumbricus rubellus and Aporrectodea caliginosa). The objective was to assess the applicability of CBRs as a practical tool in soil quality assessment of contaminated sites and as a means of a sustainable protection of earthworm fauna. Laboratory studies showed that body concentrations of Cu were generally in agreement with the chemically available CaCl₂-extractable fraction in soil, but that there was also some evidence of internal pH-related homeostatic regulation. Toxicological correlates of body Cu concentrations with adverse effects on cocoon production (fecundity) suggested an approximate sublethal internal threshold of about 40 mg kg⁻¹, with mortality occurring at about 60 mg kg⁻¹. Adult L. rubellus sampled from areas with a wide range of metal pollution showed body Cu concentrations with a minimum of 8 mg kg⁻¹ and a maximum of 60 mg kg⁻¹. Beyond this apparent physiological tolerance range, environmental management directed at optimal earthworm population survival may not be sustainable in contaminated fields. Studies of L. rubellus colonizing a metal-contaminated experimental sludge-treated field showed that a reduced rate of colonization can already be associated with an average body Cu concentration of 25 mg kg⁻¹. However, in this particular field situation mixture effects of other metals that were also present in the soil and the occurrence of avoidance behaviour during colonization may have contributed to this low internal toxicity threshold. It is concluded that the CBR approach seems to be a feasible option for use as a tool in a bioavailability-based soil quality assessment, even for essential trace metals like copper, but that further insight may be needed to establish the uncertainty and reliability of the application in environmental quality assessment and decision making.     

The effect of pH and calcium on copper availability to the springtail Folsomia candida in simplified soil solutions

The effect of pH and calcium on copper bioavailability to the springtail Folsomia candida was determined by assessing uptake kinetics upon copper exposure for 15 days in simplified soil solutions. A slight bioaccumulation of copper was observed in all treatments and controls. The effect of exposure concentration and calcium level on copper accumulation was not significant. Although pH and time slightly but significantly affected copper concentrations in the body, copper uptake rates were not significantly different from zero. This suggests that copper uptake in F. candida exposed to sub-lethal copper concentrations in soil pore water is not affected by pH and calcium.     

秦王川灌区农田土壤盐分离子特征分析

引大入秦工程实施以来,秦王川灌区土壤次生盐渍化问题日益成为人们关注的焦点。对秦王川灌区不同时空下的农田土壤可溶性盐分离子特征进行了统计分析以及对比分析,结果表明:秦王川盆地农田土壤八大离子中,阴离子以SO42-浓度最高,CO32-浓度最低,几乎为零,阳离子以Na+浓度最高,K+浓度最低,主要盐分包括Na2SO4、CaSO4、NaHCO3和Ca(HCO3)2等;土壤中不同盐分离子之间存在着一定程度的相关性,体现了盐分的沉积学特征以及其在土壤剖面上的分化关系;土壤的盐分含量在各种因素(灌溉、蒸发、降水以及人为耕作等)影响下,是一个时刻变化的动态过程,这种动态过程可能会在某一时间点达到某种平衡,但这种平衡会被新的因素的加入而打破。     

盐渍化土壤剖面盐分与养分分布特征及盐分迁移估算

针对盐渍化灌区土壤盐渍化问题,以内蒙古河套灌区下游乌拉特灌域为研究区,通过野外实测与室内试验分析结合,采用冗余分析法探讨了盐渍化改良耕地与荒地春季（4月）和秋季（10月）根层土壤（0～20 cm、20～40 cm）盐分离子与全盐、pH值、养分之间的相关关系,明确了其变化特征与数量关系,并估算了试验区改良耕地和荒地间1 m土体的盐分迁移量。结果表明,改良耕地与荒地土壤阴离子均以Cl^-为主,分别占阴离子总量的45.27%、58.78%,阳离子以Na⁺为主,分别占阳离子总量的60.67%、53.94%。荒地平均全盐含量超过7.0 g/kg,土壤盐渍化程度较重。冗余分析表明,改良耕地土壤全盐含量起主导作用的是SO■、Cl^-、Ca²⁺,荒地土壤全盐含量起主导作用的是Cl^-、Mg²⁺、Na⁺。土壤pH值变化与HCO^-₃有着密切的关系。改良耕地有效磷与Na⁺呈显著负相关（P<0...     

膜下咸水滴灌水肥盐调控对棉花盐离子、养分吸收及干物质分配的影响

【目的】探索南疆地区膜下咸水滴灌条件下水肥盐调控管理模式。【方法】设置不同淡咸水混合比例(1∶0、4∶1和2∶3)和不同施氮量(400、300 kg/hm²和200 kg/hm²)组合方案,其中淡咸水混合比例1∶0、施氮量300 kg/hm²为对照,研究了膜下咸水滴灌水肥盐调控对棉花盐离子、养分吸收及干物质分配的影响。【结果】随着灌溉水矿化度的增大,棉株体内盐离子(Na⁺、Cl^-与Ca²⁺)量呈增加趋势,其中Na⁺与Cl^-量显著增加;吸收的盐离子主要积累在茎和叶,在叶中积累量最高。灌溉水矿化度的增大对棉株N、P和K量及积累量均呈降低趋势。增施氮肥可以有效促进根系干物质的积累和植株对养分与盐离子的吸收,植株体内N和K量显著性增加,有效促进了棉花的生长;同时,增施氮肥也促进了棉株对Na⁺与Cl^-的吸收,淡咸比例4∶1混合灌溉(微咸水)茎和叶中适量的Na⁺与Cl^-积累量有利于抑制高施氮量(400 kg/hm²)营养器官(茎和叶)“徒长”,将高施氮量吸收的更多养分向生殖器官(蕾铃)分配,有利于产量的形成;而淡咸比例2∶3混合灌溉(咸水)Na⁺与Cl^-在棉株体内积累量显著增加,抑制了营养生长及养分向生殖器官的分配,不利于产量的形成。C_4:1N_H处理棉花干物质积累量蕾铃占比较对照提高1.5%,产量(6829.80 kg/hm²)达到了接近对照的水平;而C_2:3N_H处理棉花干物质积累量蕾铃占比较对照提升了0.8%,但由于盐离子在棉株体内的大量积累,单株棉花干物质积累量下降较多,因此产量增加不显著。【结论】淡咸比例4∶1混合灌溉(微咸水)适当的盐分胁迫以及合理的增施氮肥能有效地促进棉花的生长及各器官干物质的分配,在减少20%淡水使用的情况下保障了棉花产量。     

茶汤组分与金属离子的络合性能

用直接观察法、酒石酸亚铁法和铬黑 T 祛对绿茶茶汤组分与23种金属离子的络合性能进行了研究,结果表明,有22种金属离子可与茶汤组分发生络合或还原络合反应,其中有10种金属离子参与了茶多酚的络合。钙离子可与茶汤组分生成低溶解度的络合物,其溶解度及稳定性可随反应溶液 pH 升高而下降。钙络合沉淀中的主要茶汤组分是茶多酚,其中以酯型儿茶素含量最高。     

乳状液膜在金属离子测定中的分离富集作用

简要介绍乳状液膜技术在金属离子分析测定中的分离富集作用以及新的研究和应用进展状况。